When sunlight encounters a raindrop, part of the light is reflected and the rest enters the raindrop. The light is refracted at the surface of the raindrop. When this light hits the back of the raindrop, some of it is reflected off the back. When the internally reflected light reaches the surface again, once more some is internally reflected and some is refracted as it exits the drop. (The light that reflects off the drop, exits from the back, or continues to bounce around inside the drop after the second encounter with the surface, is not relevant to the formation of the primary rainbow. ) The overall effect is that part of the incoming light is reflected back over the range of 0° to 42°, with the most intense light at 42°. This angle is independent of the size of the drop, but does depend on its refractive index. Seawater has a higher refractive index than rain water, so the radius of a "rainbow" in sea spray is smaller than a true rainbow. This is visible to the naked eye by a misalignment of these bows.
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